Cobalt and iron co-doped ZnSe nanocrystals:Mid-IR luminescence at room temperature | |
Shi, Huawei1,2; Cui, Xiaoxia1,2![]() ![]() ![]() ![]() ![]() | |
作者部门 | 先进光电与生物材料研究室 |
2020-05 | |
发表期刊 | Journal of Luminescence
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ISSN | 00222313 |
卷号 | 221 |
产权排序 | 1 |
摘要 | Fe:Co:ZnSe nanocrystals with different co-doping ratios of Fe2+/Co2+ ions were fabricated by hydrothermal synthesis. The facile method used in the present work avoids the mid-infrared quench effect induced by the organic molecular introduced in the past preparation process. These nanocrystals are spherical in shape and exhibit a cubic sphalerite structure with an average grain size of about 15 nm. Through the energy conversion between Co2+ and Fe2+ ions, mid-infrared fluorescences at 3.3 μm and 4.4 μm were detected under 1550 nm laser excitation at room temperature. The fluorescence band of 4.4 μm in the Fe:Co:ZnSe nanocrystals is thought to be an overlapping emission involving the peak centered at 4648 nm corresponding to the Co2+:4T1 (F) → 4T2 (F) energy transition and the peak centered at 4273 nm corresponding to Fe2+:5T2 (D) → 5E (D) energy transition. These high-quality optically active nanomaterials show potential applications in mid-infrared devices such as composite fiber-amplifiers and lasers materials. © 2020 |
关键词 | Mid-infrared Transition metal ions Energy transfer Fe:Co:ZnSe nanocrystals Photoluminescence |
DOI | 10.1016/j.jlumin.2020.117102 |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:000518457400039 |
出版者 | Elsevier B.V. |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.opt.ac.cn/handle/181661/93245 |
专题 | 光子功能材料与器件研究室 |
通讯作者 | Guo, Haitao |
作者单位 | 1.State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Science (CAS), Xi'an; Shaanxi; 710119, China; 2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences (UCAS), Beijing; 100049, China; 3.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan; Hubei; 430070, China; 4.Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan; Shanxi; 030006, China |
推荐引用方式 GB/T 7714 | Shi, Huawei,Cui, Xiaoxia,Xiao, Xusheng,et al. Cobalt and iron co-doped ZnSe nanocrystals:Mid-IR luminescence at room temperature[J]. Journal of Luminescence,2020,221. |
APA | Shi, Huawei.,Cui, Xiaoxia.,Xiao, Xusheng.,Xu, Yantao.,Liu, Chao.,...&Guo, Haitao.(2020).Cobalt and iron co-doped ZnSe nanocrystals:Mid-IR luminescence at room temperature.Journal of Luminescence,221. |
MLA | Shi, Huawei,et al."Cobalt and iron co-doped ZnSe nanocrystals:Mid-IR luminescence at room temperature".Journal of Luminescence 221(2020). |
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文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Cobalt and iron co-d(1988KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 请求全文 |
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