Synthesis of a terpolymer containing fluorene, side chain conjugated thiophene and benzothiadiazole and its applications in photovoltaic devices | |
Liu, Hongli1; Qu, Bo2; Chen, Jian1; Cong, Zhiyuan1; An, Zhongwei1; Gao, Chao1,3; Xiao, Lixin2; Chen, Zhijian2; Gong, Qihuang2; Guo W(国外) | |
作者部门 | 材料中心 |
2013-06-05 | |
发表期刊 | JOURNAL OF APPLIED POLYMER SCIENCE
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ISSN | 1612-2011 |
卷号 | 128期号:5页码:3250-3255 |
摘要 | A terpolymer (POTVTh-8FO-DBT) containing fluorene, side chain conjugated thiophene and 4,7-dithieny-2,1,3-benzothiadiazole was synthesized by palladium-catalyzed Suzuki coupling method. The polymer is soluble in common organic solvents. The thermal, absorption, and electrochemical properties of the polymer were examined. Photovoltaic properties of POTVTh-8FO-DBT were studied by fabricating the polymer solar cells (PSCs) based on POTVTh-8FO-DBT as donor and [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) as acceptor. With the weight ratio of POTVTh-8FO-DBT : PC61BM of 1 : 1 and the active layer thickness of 80 nm, the power conversion efficiency (PCE) of the device reached 0.47% with Voc = 0.61 V, Jsc = 1.61 mA/cm2, and filled factor (FF) = 0.49 under the illumination of AM 1.5, 100 mW/cm2. The results indicated that this polymer was promising donor candidates in the application of PSCs. (c) 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 |
文章类型 | Article |
关键词 | Copolymers Optical And Photovoltaic Applications Synthesis And Processing |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1002/app.38528 |
收录类别 | SCI ; EI |
关键词[WOS] | POLYMER SOLAR-CELLS ; OPEN-CIRCUIT VOLTAGE ; LOW-BANDGAP POLYMER ; TANDEM POLYMER ; DONOR ; EFFICIENCY ; POLYTHIOPHENES ; ENHANCEMENT ; COPOLYMERS |
语种 | 英语 |
WOS研究方向 | Polymer Science |
WOS类目 | Polymer Science |
WOS记录号 | WOS:000315910500082 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.opt.ac.cn/handle/181661/22066 |
专题 | 光子功能材料与器件研究室 |
通讯作者 | Guo W(国外) |
作者单位 | 1.Xian Modern Chem Res Inst, Xian 710065, Shaanxi, Peoples R China 2.Peking Univ, Dept Phys, State Key Lab Artificial Microstruct & Mesoscop P, Beijing 100871, Peoples R China 3.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Hongli,Qu, Bo,Chen, Jian,et al. Synthesis of a terpolymer containing fluorene, side chain conjugated thiophene and benzothiadiazole and its applications in photovoltaic devices[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2013,128(5):3250-3255. |
APA | Liu, Hongli.,Qu, Bo.,Chen, Jian.,Cong, Zhiyuan.,An, Zhongwei.,...&国外.(2013).Synthesis of a terpolymer containing fluorene, side chain conjugated thiophene and benzothiadiazole and its applications in photovoltaic devices.JOURNAL OF APPLIED POLYMER SCIENCE,128(5),3250-3255. |
MLA | Liu, Hongli,et al."Synthesis of a terpolymer containing fluorene, side chain conjugated thiophene and benzothiadiazole and its applications in photovoltaic devices".JOURNAL OF APPLIED POLYMER SCIENCE 128.5(2013):3250-3255. |
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