Cu-MOFs derived three-dimensional Cu1.81S@C for high energy storage performance | |
Chen, Yanan2; Zhao, Yuanbo2; He, Weijun2; Liu, Yanan2; Xing, Hongna2; Zhu, Xiuhong1,2; Guo, Yanqun3; Feng, Juan2; Liao, Chunyan2; Zong, Yan2; Li, Xinghua2; Zheng, Xinliang2 | |
作者部门 | 瞬态光学研究室 |
2023-12 | |
发表期刊 | Materials Today Communications |
ISSN | 23524928 |
卷号 | 37 |
产权排序 | 1 |
摘要 | Significant volume changes and slow ionic transport during charge/discharge processes restrict the improvement of electrochemical performance for CuxS (x = 1–2). Herein, a new strategy by introducing Cu-BTC (copper(II)-benzene-1,3,5-tricarboxylate) as a processor to derive three-dimensional Cu1.81S@C using green sulfurization and calcination methods is proposed. Benefiting from the high electrical conductivity, multistage pore size structure and stable structure brought by the conductive carbon skeleton after calcination, Cu1.81S@C-650oC exhibits a high specific capacitance of 291.1 F g-1 at a current density of 1 A g-1 and a superior rate capability of 83.6 % at a current density of 10 A g-1. In addition, the assembled asymmetric supercapacitor (Cu1.81S@C-650oC//AC ASC) also shows impressive performances, such as an energy density up to 16 Wh kg-1 at a power density of 352 W kg-1 and an excellent cycling stability of 93.1 % over 5000 cycles at a current density of 2 A g-1. This work demonstrates that the Cu-BTC-derived Cu1.81S@C is an attractive material with potential applications in energy storage devices. © 2023 Elsevier Ltd |
关键词 | Electrochemical performance Cu-BTC Cu1.81S@C Green sulfurization Asymmetric supercapacitor |
DOI | 10.1016/j.mtcomm.2023.106955 |
收录类别 | SCI ; EI |
语种 | 英语 |
WOS记录号 | WOS:001116754400001 |
出版者 | Elsevier Ltd |
EI入藏号 | 20233614672458 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.opt.ac.cn/handle/181661/96766 |
专题 | 瞬态光学研究室 |
通讯作者 | Zhu, Xiuhong; Li, Xinghua |
作者单位 | 1.State Key Laboratory of Transient Optics and Photonics, Chinese Academy of Sciences, Xi'an; 710119, China; 2.School of Physics, Northwest University, Xi'an; 710069, China; 3.Shanghai Key Laboratory of High Temperature Superconductors, Shanghai University, Shanghai; 200444, China |
推荐引用方式 GB/T 7714 | Chen, Yanan,Zhao, Yuanbo,He, Weijun,et al. Cu-MOFs derived three-dimensional Cu1.81S@C for high energy storage performance[J]. Materials Today Communications,2023,37. |
APA | Chen, Yanan.,Zhao, Yuanbo.,He, Weijun.,Liu, Yanan.,Xing, Hongna.,...&Zheng, Xinliang.(2023).Cu-MOFs derived three-dimensional Cu1.81S@C for high energy storage performance.Materials Today Communications,37. |
MLA | Chen, Yanan,et al."Cu-MOFs derived three-dimensional Cu1.81S@C for high energy storage performance".Materials Today Communications 37(2023). |
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Cu-MOFs derived thre(8529KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 请求全文 |
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