| Optical properties of a novel neodymium pentafluoropropionate binuclear complex | |
Gao, Chao1,2; Cui, Kai1; She, Jiangbo1; Hou, Chaoqi1 ; Guo, Hongyan2; Zhao, Wei1; Wei, Wei1,3; Peng, Bo1,3
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| 2009-04-20 | |
| 发表期刊 | INORGANICA CHIMICA ACTA
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| 卷号 | 362期号:6页码:2001-2005 |
| 摘要 | A novel neodymium pentafluoropropionate binuclear complex, Nd(C(2)F(5)COO)(3)Dipy (Dipy: 2,2'-dipyridyl), was synthesized and characterized by single-crystal X-ray diffraction. At a concentration of 0.2 M in DMSO-d(6), the Judd-Ofelt parameters (Omega(2), Omega(4), Omega(6)) were calculated from the UV-Vis spectrum. According to the small value of Omega(2) and the zero splitting energy of (4)F/(3/2) level, a symmetric ligand field of the complex was confirmed in DMSO-d(6). Strong emission of the complex in DMSO-d(6) at 1057 nm with a decay time about 1.3 mu s were detected when excited at 800 nm pumped by a laser diode. The stimulated emission cross-section of (4)F(3/2) -> (4)I(11/2) fluorescence transition was 2.36 x 10 (20) cm(2) and comparable with some laser glasses, which indicated good radiative properties of this neodymium pentafluoropropionate binuclear complex in liquid matrix. (c) 2008 Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Neodymium Complex Crystal Structure Judd-ofelt Theory Optical Property Emission Cross-section |
| 学科领域 | 激光材料及工作物质 |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.ica.2008.09.033 |
| 收录类别 | SCI |
| 关键词[WOS] | ND3+ COMPLEXES ; LUMINESCENCE ; IONS ; EMISSION ; PHOTOLUMINESCENCE ; LANTHANIDES ; INTENSITIES ; DMSO-D(6) ; MAGNETISM ; SPECTRA |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| WOS记录号 | WOS:000265299200050 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/7966 |
| 专题 | 光子功能材料与器件研究室 |
| 作者单位 | 1.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China 2.Xian Modern Chem Res Inst, Photoelectron Mat Ctr, Xian 710065, Shaanxi, Peoples R China 3.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Chao,Cui, Kai,She, Jiangbo,et al. Optical properties of a novel neodymium pentafluoropropionate binuclear complex[J]. INORGANICA CHIMICA ACTA,2009,362(6):2001-2005. |
| APA | Gao, Chao.,Cui, Kai.,She, Jiangbo.,Hou, Chaoqi.,Guo, Hongyan.,...&Peng, Bo.(2009).Optical properties of a novel neodymium pentafluoropropionate binuclear complex.INORGANICA CHIMICA ACTA,362(6),2001-2005. |
| MLA | Gao, Chao,et al."Optical properties of a novel neodymium pentafluoropropionate binuclear complex".INORGANICA CHIMICA ACTA 362.6(2009):2001-2005. |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Optical properties o（789KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 请求全文 | |
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