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Synthesis of NASICON-type Mg_(0.5)Zr_2(PO_4)_3 magnesium ion solid electrolyte by coprecipitation method
Alternative Title共沉淀法制备NASICON型Mg_(0.5)Zr_2(PO_4)_3镁离子固态电解质
Li Wenlong1,2; Liu Huan1,2; Yang Liqing1; Guo Bin1,2; Hu Weijie1,2; Wang Haojing1; Wang Haojing (hjwang@opt.cn)
Department等离子体物理化学应用技术研究中心
2017
Source PublicationJournal of Functional Materials
ISSN10019731
Volume48Issue:1Pages:1195-1198,1203
Contribution Rank1
Abstract

Samples of Mg_(0.5)Zr_2(PO_4)_3 compound with pure NASICON-phase were obtained by coprecipitation method with magnesium nitrate,zirconium acetate and diammonium hydrogen phosphate as raw material.The Mg_(0.5)Zr_2(PO_4)_3(MZP)precursor powders were sintered via pressureless sintering and characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM)and electrochemical impedance spectroscopy(EIS). The results show that samples sintered at 750 ℃ by the pressureless sintering showed the highest total conductivity of 4.67*10~(-6) S/cm and its density reached 90% of theoretical density.The activation energy of the samples is 0.098 eV.The studies have shown that Mg_(0.5)Zr_2(PO_4)_3 is a promising magnesium ion conductive materials and of great significance for the research of solid-state magnesium ion battery in the future.

Indexed ByCSCD
Language中文
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Document Type期刊论文
Identifierhttp://ir.opt.ac.cn/handle/181661/28931
Collection复合材料与器件先进制造研发中心
Corresponding AuthorWang Haojing (hjwang@opt.cn)
Affiliation1.State Key Laboratory of Transient Optics and Photonics, Xian Institute of Optics and Precision Mechanics of CAS, Xi'an, Shaanxi 710119, China
2.University of Chinese Academy of Sciences, Beijing; 100049, China
Recommended Citation
GB/T 7714
Li Wenlong,Liu Huan,Yang Liqing,et al. Synthesis of NASICON-type Mg_(0.5)Zr_2(PO_4)_3 magnesium ion solid electrolyte by coprecipitation method[J]. Journal of Functional Materials,2017,48(1):1195-1198,1203.
APA Li Wenlong.,Liu Huan.,Yang Liqing.,Guo Bin.,Hu Weijie.,...&Wang Haojing .(2017).Synthesis of NASICON-type Mg_(0.5)Zr_2(PO_4)_3 magnesium ion solid electrolyte by coprecipitation method.Journal of Functional Materials,48(1),1195-1198,1203.
MLA Li Wenlong,et al."Synthesis of NASICON-type Mg_(0.5)Zr_2(PO_4)_3 magnesium ion solid electrolyte by coprecipitation method".Journal of Functional Materials 48.1(2017):1195-1198,1203.
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