| Facile synthesis of porous nitrogen-doped holey graphene as an efficient metal-free catalyst for the oxygen reduction reaction | |
| Qin, Li1,2,5; Ding, Ruimin1,2; Wang, Huixiang1,2,5; Wu, Jianghong1,2,5; Wang, Conghui1,2,5; Zhang, Chenghua1,3; Xu, Yao4; Wang, Liancheng1,2; Lv, Baoliang1,2 | |
| 作者部门 | 等离子体物理化学应用技术研究中心 |
| 2017 | |
| 发表期刊 | NANO RESEARCH
 |
| ISSN | 1998-0124 |
| 卷号 | 10期号:1页码:305-319 |
| 产权排序 | 4 |
| 摘要 | Nitrogen-doped graphene is a promising candidate for the replacement of noble metal-based electrocatalysts for oxygen reduction reactions (ORRs). The addition of pores and holes into nitrogen-doped graphene enhances the ORR activity by introducing abundant exposed edges, accelerating mass transfer, and impeding aggregation of the graphene sheets. Herein, we present a straightforward but effective strategy for generating porous holey nitrogen-doped graphene (PHNG) via the pyrolysis of urea and magnesium acetate tetrahydrate. Due to the combined effects of the in situ generated gases and MgO nanoparticles, the synthesized PHNGs featured not only numerous out-of-plane pores among the crumpled graphene sheets, but also interpenetrated nanoscale (5-15 nm) holes in the assembled graphene. Moreover, the nitrogen doping configurations of PHNG were optimized by post-thermal treatments at different temperatures. It was found that the overall content of pyridinic and quaternary nitrogen positively correlates with the ORR activity; in particular, pyridinic nitrogen generates the most desirable characteristics for the ORR. This work reveals new routes for the synthesis of PHNG-based materials and elucidates the contributions of various nitrogen species to ORRs. |
| 文章类型 | Article |
| 关键词 | Porous Holey N-doped Graphene In Situ Templates Post-thermal Treatment Oxygen Reduction Reaction |
| 学科领域 | Chemistry, Physical |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1007/s12274-016-1293-5 |
| 收录类别 | SCI |
| 关键词[WOS] | ACTIVE-SITES ; CARBON MATERIALS ; ENERGY-STORAGE ; FUEL-CELLS ; PERFORMANCE ; ELECTROCATALYST ; NANORIBBONS ; COMPOSITES ; ELECTRODES ; FRAMEWORKS |
| 语种 | 英语 |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 项目资助者 | National Natural Science Foundation of China(21503253 ; Natural Science Foundation of Shan-Xi province of China(2015011010) ; Youth Innovation Promotion Association CAS(2015141) ; 21403276 ; 91545109) |
| WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied |
| WOS记录号 | WOS:000390066000027 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/28577 |
| 专题 | 复合材料与器件先进制造研发中心 |
| 作者单位 | 1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China 3.Synfuels China Technol Co Ltd, Beijing 101407, Peoples R China 4.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qin, Li,Ding, Ruimin,Wang, Huixiang,et al. Facile synthesis of porous nitrogen-doped holey graphene as an efficient metal-free catalyst for the oxygen reduction reaction[J]. NANO RESEARCH,2017,10(1):305-319. |
| APA | Qin, Li.,Ding, Ruimin.,Wang, Huixiang.,Wu, Jianghong.,Wang, Conghui.,...&Lv, Baoliang.(2017).Facile synthesis of porous nitrogen-doped holey graphene as an efficient metal-free catalyst for the oxygen reduction reaction.NANO RESEARCH,10(1),305-319. |
| MLA | Qin, Li,et al."Facile synthesis of porous nitrogen-doped holey graphene as an efficient metal-free catalyst for the oxygen reduction reaction".NANO RESEARCH 10.1(2017):305-319. |
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