Effects of fluorine on the properties of Yb/Ce co-doped aluminosilicate preforms prepared by MCVD with organic chelate precursor doping technique

doi:10.1016/j.jnoncrysol.2016.07.016

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	Effects of fluorine on the properties of Yb/Ce co-doped aluminosilicate preforms prepared by MCVD with organic chelate precursor doping technique
	Li, Weinan; Luo, Rong; Li, Chao; Gao, Song; Chang, Chang; Hou, Chaoqi; Zhao, Baoyin; Hou, Chaoqi (houchaoqi@opt.ac.cn)
作者部门	瞬态光学技术国家重点实验室
	2016-10-01
发表期刊	JOURNAL OF NON-CRYSTALLINE SOLIDS
ISSN	0022-3093
卷号	449 页码:119-124
产权排序	1
摘要	Co-doped Yb/Ce aluminosilicate fiber preforms with less than 1 We% fluorine were prepared by MCVD with organic chelate precursor doping technique at 1400 degrees C. Fluorine content characterized by electron probe microanalysis decreased with increasing SiF4 flow and flow ratio of SiF4/SiCl4. Under maximum SiF4 flow the concentrations of Yb2O3 and CeO2 in the perform core were only as much as 17% and 25% under minimum SiF4 flow, respectively, but smaller refractive index change was only shown in fiber core. The reason was that the reaction of SiF4 with Al2O3,Yb2O3,CeO2 were intensified with increasing flow ratio of SiF4/SiCl4 and then resulted in producing more exhaust gas such as AlF3, YbF3 and CeF4. Raman spectra of core glasses with <0.5 Wt% fluorine present different Raman shifts from F doped silica glass with 1-3.3 Wt% fluorine: 945 cm(-1) of Si-F stretching bond was not observed, and with growth of fluorine content antisymmetric stretching vibrations of Si-O-Si linkages split from an envelope of 1188 cm(-1) into two peaks or three peaks shifted higher frequency. At the same time, Boson peak near 125 cm(-1) shifted to lower frequency. They were attributed to some minor changes of glass's network structure due to introducing lower fluorine into core glasses. On base of bonding energymeasured by X-ray photoelectric spectroscopy, the plane graph describing the complex bonding distribution with F in core was supplied to in order to illustrate network structure change. (C) 2016 Elsevier B.V. All rights reserved.
文章类型	Article
关键词	Raman Spectra Chelate Precursor Yb/ce Codoped Silica Glass Antisymmetric Stretching Vibrations
WOS标题词	Science & Technology ; Technology
DOI	10.1016/j.jnoncrysol.2016.07.016
收录类别	SCI ; EI
关键词[WOS]	SINGLE-MODE OPERATION ; POWER FIBER LASERS ; OPTICAL-FIBERS ; FABRICATION ; AMPLIFIER ; AREA ; SILICA
语种	英语
WOS研究方向	Materials Science
项目资助者	Major Program of the National Natural Science Foundation of China(61138007)
WOS类目	Materials Science, Ceramics ; Materials Science, Multidisciplinary
WOS记录号	WOS:000383298000017
引用统计	被引频次：12[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.opt.ac.cn/handle/181661/28288
专题	瞬态光学研究室
通讯作者	Hou, Chaoqi (houchaoqi@opt.ac.cn)
作者单位	Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Peoples R China
推荐引用方式 GB/T 7714	Li, Weinan,Luo, Rong,Li, Chao,et al. Effects of fluorine on the properties of Yb/Ce co-doped aluminosilicate preforms prepared by MCVD with organic chelate precursor doping technique[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS,2016,449:119-124.
APA	Li, Weinan.,Luo, Rong.,Li, Chao.,Gao, Song.,Chang, Chang.,...&Hou, Chaoqi .(2016).Effects of fluorine on the properties of Yb/Ce co-doped aluminosilicate preforms prepared by MCVD with organic chelate precursor doping technique.JOURNAL OF NON-CRYSTALLINE SOLIDS,449,119-124.
MLA	Li, Weinan,et al."Effects of fluorine on the properties of Yb/Ce co-doped aluminosilicate preforms prepared by MCVD with organic chelate precursor doping technique".JOURNAL OF NON-CRYSTALLINE SOLIDS 449(2016):119-124.

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