| Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser | |
Zhang, Guofang1; She, Jiangbo2 ; Han, Kai1; Nie, Rongzhi2; Li, Dongdong3; Peng, Bo2
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| 2015-11-01 | |
| 发表期刊 | OPTICAL MATERIALS
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| 卷号 | 49页码:343-347 |
| 摘要 | A novel binuclear neodymium complex Nd(CF3COO)(3)center dot(Ph3PO)(2) (Ph3PO: triphenylphosphine oxide) with high stimulated emission cross-section was presented. The molecular structure of the complex was characterized by single-crystal X-ray diffraction. The optical properties of the complex in liquid medium were studied. From the absorption and luminescence spectra, the Judd-Ofelt parameters of Nd (CF3COO)(3)center dot(Ph3PO)(2) in phosphorus oxychloride were obtained. Based on the crystal structure, the effects of crystal field and bonding valence properties on three intensity parameters Omega(t)(t = 2, 4, 6) and emission cross-section were analyzed in detail. The emission cross-section of E-4(3/2) -> I-4(11/2) fluorescence transition (2.78 x 10(-2) cm(2)) of the new neodymium compound was higher than those of other Nd(III) complexes and even comparable with some laser glasses. (C) 2015 Elsevier BM. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Crystal Structure Optical Property Judd-ofelt Theory Liquid Laser Emission Cross-section |
| 学科领域 | Materials Science, Multidisciplinary |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| DOI | 10.1016/j.optmat.2015.10.002 |
| 收录类别 | SCI ; EI |
| 关键词[WOS] | RARE-EARTH IONS ; TRANSITION-PROBABILITIES ; LANTHANIDE COMPLEXES ; STIMULATED-EMISSION ; BORATE GLASSES ; ND3+ IONS ; LUMINESCENT ; SPECTROSCOPY ; INTENSITIES ; ABSORPTION |
| 语种 | 英语 |
| WOS研究方向 | Materials Science ; Optics |
| 项目资助者 | National Natural Science Foundation of China (NSFC)(61108061 ; West Light Foundation of The Chinese Academy of Sciences ; 61308086 ; 21171112) |
| WOS类目 | Materials Science, Multidisciplinary ; Optics |
| WOS记录号 | WOS:000364255100054 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/27264 |
| 专题 | 光子功能材料与器件研究室 |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Chem & Chem Engn, MOE, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China 2.Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Shaanxi, Peoples R China 3.Xian Univ Post & Telecommun, Sch Elect Engn, Xian 710121, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Guofang,She, Jiangbo,Han, Kai,et al. Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser[J]. OPTICAL MATERIALS,2015,49:343-347. |
| APA | Zhang, Guofang,She, Jiangbo,Han, Kai,Nie, Rongzhi,Li, Dongdong,&Peng, Bo.(2015).Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser.OPTICAL MATERIALS,49,343-347. |
| MLA | Zhang, Guofang,et al."Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser".OPTICAL MATERIALS 49(2015):343-347. |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Optical properties o（630KB） | 期刊论文 | 作者接受稿 | 限制开放 | CC BY-NC-SA | 请求全文 | |
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