| Optical properties of Nd(TTA)(3)(TPPO)(2) doped polymer and its potential laser application | |
Lu, Jiabao1; Yu, Kehan1; Wang, Hongyu1; He, Junfang2 ; Cheng, Guanghua2; Qin, Chunyang1; Lin, Jianming1; Wei, Wei1; Peng, Bo1,2
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| 2008-06-01 | |
| 发表期刊 | OPTICAL MATERIALS
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| 卷号 | 30期号:10页码:1531-1537 |
| 摘要 | In this work, the Nd(III) complex doped PMMA with high stimulated emission cross-section, which is one of the most important parameters for laser design, was presented. The molecular structure of the complex, Nd(TTA)(3)(TPPO)(2) (HTTA: 2-thenoyltrifluoroacetone, TPPO: triphenylphosphine oxide), was characterized by single-crystal X-ray diffraction. From the absorption and luminescence spectra, the Judd-Ofelt parameters (Omega(2), Omega(4) and 26) of the Nd3+ ion in PMMA were obtained and the radiative properties were discussed using Judd-Ofelt theory. The stimulated emission cross-section of the emission band at 1.060 mu m is 2.75 x 10(-20) cm(2), which is higher than that of other Nd(III) complex doped organic systems and even comparable with some laser glasses. On the basis of the experimental data and Judd-Ofelt analysis, the F-4(3/2) -> I-4(11/2) transition of the Nd3+ ion in PMMA can be considered as a possible laser transition. (c) 2007 Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Crystal Structure Judd-ofelt Theory Optical Properties Emission Cross-section |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| DOI | 10.1016/j.optmat.2007.09.009 |
| 收录类别 | SCI ; EI |
| 关键词[WOS] | RARE-EARTH IONS ; POLY(METHYL METHACRYLATE) ; TRANSITION-PROBABILITIES ; SPECTROSCOPIC PROPERTIES ; LANTHANIDE COMPLEXES ; STIMULATED-EMISSION ; QUANTUM-EFFICIENCY ; ABSORPTION-SPECTRA ; GLASS COMPOSITION ; BORATE GLASSES |
| 语种 | 英语 |
| WOS研究方向 | Materials Science ; Optics |
| WOS类目 | Materials Science, Multidisciplinary ; Optics |
| WOS记录号 | WOS:000256821900012 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/25205 |
| 专题 | 瞬态光学研究室 |
| 作者单位 | 1.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Jiabao,Yu, Kehan,Wang, Hongyu,et al. Optical properties of Nd(TTA)(3)(TPPO)(2) doped polymer and its potential laser application[J]. OPTICAL MATERIALS,2008,30(10):1531-1537. |
| APA | Lu, Jiabao.,Yu, Kehan.,Wang, Hongyu.,He, Junfang.,Cheng, Guanghua.,...&Peng, Bo.(2008).Optical properties of Nd(TTA)(3)(TPPO)(2) doped polymer and its potential laser application.OPTICAL MATERIALS,30(10),1531-1537. |
| MLA | Lu, Jiabao,et al."Optical properties of Nd(TTA)(3)(TPPO)(2) doped polymer and its potential laser application".OPTICAL MATERIALS 30.10(2008):1531-1537. |
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| Optical properties o（306KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 请求全文 | |
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