| Synthesis, crystal structure, and optical properties of a novel rare-earth complex Nd(C(2)F(5)COO)(3) center dot Phen | |
She, Jiangbo2,3 ; Gao, Chao2; Cui, Kai2; Hou, Chaoqi2; Zhao, Wei2; Wei, Wei1; Peng, B.1,2
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| 2008-12-01 | |
| 发表期刊 | STRUCTURAL CHEMISTRY
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| 卷号 | 19期号:6页码:905-910 |
| 摘要 | A novel neodymium pentafluoropropionate binuclear complex, Nd(C(2)F(5)COO)(3) center dot Phen (Phen: 1,10-phenanthroline), was synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR spectra, UV-Vis-NIR absorption, and PL spectra. Single-crystal data show that the complex bears centrosymmetric dinuclear structure with a planar ligand configuration. Four carboxylato groups act as eta(2)-chelate-mu(2)-carboxylato-k(1)O: k(1)O'-bridge-ligands, the other two occupy the terminal position as monodentate ligands. At the same time, the C-O distances appear averaged which indicate the three atoms of carboxylato forming electron-conjugate system. Hydrogen bond and pi-pi-stacking link the binuclear to two-dimensional sheet. Optical spectra exhibit the complex possesses typical Nd(III) ion absorption and photoluminescence emission. |
| 文章类型 | Article |
| 关键词 | Neodymium Pentafluoropropionate Crystal Structure 1 Luminescent Property 10-phenanthroline |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1007/s11224-008-9357-0 |
| 收录类别 | SCI |
| 关键词[WOS] | EMISSION CROSS-SECTION ; SOL-GEL METHOD ; SILICA MATRIX ; LANTHANIDE(III) COMPLEXES ; LASER ; ND ; FLUORESCENCE ; NEODYMIUM ; EUROPIUM ; NM |
| 语种 | 英语 |
| WOS研究方向 | Chemistry ; Crystallography |
| WOS类目 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Crystallography |
| WOS记录号 | WOS:000261037700006 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/25202 |
| 专题 | 光子功能材料与器件研究室 |
| 作者单位 | 1.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Shaanxi, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | She, Jiangbo,Gao, Chao,Cui, Kai,et al. Synthesis, crystal structure, and optical properties of a novel rare-earth complex Nd(C(2)F(5)COO)(3) center dot Phen[J]. STRUCTURAL CHEMISTRY,2008,19(6):905-910. |
| APA | She, Jiangbo.,Gao, Chao.,Cui, Kai.,Hou, Chaoqi.,Zhao, Wei.,...&Peng, B..(2008).Synthesis, crystal structure, and optical properties of a novel rare-earth complex Nd(C(2)F(5)COO)(3) center dot Phen.STRUCTURAL CHEMISTRY,19(6),905-910. |
| MLA | She, Jiangbo,et al."Synthesis, crystal structure, and optical properties of a novel rare-earth complex Nd(C(2)F(5)COO)(3) center dot Phen".STRUCTURAL CHEMISTRY 19.6(2008):905-910. |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Synthesis, crystal s（298KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 请求全文 | |
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