| Synthesis and Optical Properties of Nd(III) Perfluoro-Carboxylate Complexes with 2,2 '-Bipyridine | |
She Jiang-bo2; Li Dong-dong3; Wang Peng-fei2; Zhu Yong-gang2; Wei Wei1; Peng Bo1,2
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| 2012-04-01 | |
| 发表期刊 | SPECTROSCOPY AND SPECTRAL ANALYSIS
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| 卷号 | 32期号:4页码:1047-1050 |
| 摘要 | A series of neodymium complexes, Nd(CF3COO)(3) center dot Dipy, Nd(C2F5COO)(3) center dot Dipy and Nd(C3F7COO)(3) center dot Dipy were synthesized and characterized by FTIR spectra, elemental analysis, thermogravimetric analysis, UV-Vis-NIR absorption spectra and PL spectra. The decomposition temperature was found to be more than 260 degrees C and maximum weight losses rates above 340 degrees C which indicate that they have good thermal stability. The low vibrational energy C-F bonds were used to replace the C-H bonds in organic group for improving the optical properties of materials. The length of carbon chain and the coordination structure of Nd(III) affect the absorption transition strength. According to the UV-Vis-NIR absorption spectra, the Judd-Ofelt parameters were calculated and the radiative properties were also presented. The stimulated emission cross-sections of the Nd(CF3COO)(3) center dot Dipy, Nd(C2F5COO)(3) center dot Dipy and Nd(C3F7COO)(3) center dot Dipy were 3. 63 X 10(-20), 2. 36 X 10(-20) and 1.49 X 10(-20) cm(2) respectively, which were as good as some reported inorganic materials. These complexes will be a series of promising materials for liquid laser application. |
| 文章类型 | Article |
| 关键词 | Neodymium Complex Liquid Laser Judd-ofelt Theory Stimulated Emission Cross-sections |
| WOS标题词 | Science & Technology ; Technology |
| DOI | 10.3964/j.issn.1000-0593(2012)04-1047-04 |
| 收录类别 | SCI ; EI |
| 关键词[WOS] | NEODYMIUM ; LASER ; ND3+ ; IONS |
| 语种 | 中文 |
| WOS研究方向 | Spectroscopy |
| WOS类目 | Spectroscopy |
| WOS记录号 | WOS:000302450000042 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/24036 |
| 专题 | 光子功能材料与器件研究室 |
| 作者单位 | 1.Nanjing Univ Posts & Telecommun, Inst Adv Mat, Nanjing 210003, Peoples R China 2.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Peoples R China 3.Xian Univ Posts & Telecommun, Sch Elect Engn, Xian 710061, Peoples R China |
| 推荐引用方式 GB/T 7714 | She Jiang-bo,Li Dong-dong,Wang Peng-fei,et al. Synthesis and Optical Properties of Nd(III) Perfluoro-Carboxylate Complexes with 2,2 '-Bipyridine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2012,32(4):1047-1050. |
| APA | She Jiang-bo,Li Dong-dong,Wang Peng-fei,Zhu Yong-gang,Wei Wei,&Peng Bo.(2012).Synthesis and Optical Properties of Nd(III) Perfluoro-Carboxylate Complexes with 2,2 '-Bipyridine.SPECTROSCOPY AND SPECTRAL ANALYSIS,32(4),1047-1050. |
| MLA | She Jiang-bo,et al."Synthesis and Optical Properties of Nd(III) Perfluoro-Carboxylate Complexes with 2,2 '-Bipyridine".SPECTROSCOPY AND SPECTRAL ANALYSIS 32.4(2012):1047-1050. |
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| Synthesis and Optica（1283KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY | 请求全文 | |
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