| Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers | |
Qiu, Xiaoming1; Yu, Kehan1; Lu, Jiabao1; Gao, Chao2; Hou, Chaoqi2 ; He, Junfang2; Wei, Wei1; Peng, Bo1,2
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| 作者部门 | 瞬态光学国家重点实验室 |
| 2008-10-01 | |
| 发表期刊 | OPTICAL MATERIALS
 |
| ISSN | 0925-3467 |
| 卷号 | 31期号:2页码:117-121 |
| 摘要 | A liquid solution on the basis of dissolving a novel tetranuclear neodymium complex Nd(4)(TTA)(10)O(12)H(22) (HTTA: 2-thenoyltrifluoroacetone) in polytrifluorochloroethylene oil was presented. The molecular structure of the complex was characterized by single-crystal X-ray diffraction. The optical properties of the liquid medium were studied. Enhanced emission was observed at 1064 nm when excited at 340 urn due to efficient energy transfer from T-FA to the Nd(3+) ions and the mechanism for energy transfer process was discussed in detail. The obtained fluorescent lifetime was 1.7 mu s and the quantum yield Value was 0.63%, which compare well with some other organic liquid media reported previously. Besides, this liquid shows outstanding properties with no toxicity and causticity, nonvolatility and high stability. (C) 2008 Elsevier B.V. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Crystal Structure Optical Properties Lifetime Liquid Laser |
| 学科领域 | 物理科学和化学 |
| WOS标题词 | Science & Technology ; Technology ; Physical Sciences |
| DOI | 10.1016/j.optmat.2008.01.009 |
| 收录类别 | SCI ; EI |
| 关键词[WOS] | RARE-EARTH IONS ; RADIATIONLESS TRANSITION ; LANTHANIDE COMPLEXES ; OPTICAL-FIBER ; LUMINESCENCE ; GLASS ; ND ; RELAXATION ; EMISSION ; LIGANDS |
| 语种 | 英语 |
| WOS研究方向 | Materials Science ; Optics |
| WOS类目 | Materials Science, Multidisciplinary ; Optics |
| WOS记录号 | WOS:000261822200001 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.opt.ac.cn/handle/181661/11029 |
| 专题 | 瞬态光学研究室 |
| 作者单位 | 1.Fudan Univ, State Key Lab Adv Photon Mat & Devices, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, State Key Lab Transient Opt & Photon, Xian Inst Opt & Precis Mech, Xian 710119, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiu, Xiaoming,Yu, Kehan,Lu, Jiabao,et al. Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers[J]. OPTICAL MATERIALS,2008,31(2):117-121. |
| APA | Qiu, Xiaoming.,Yu, Kehan.,Lu, Jiabao.,Gao, Chao.,Hou, Chaoqi.,...&Peng, Bo.(2008).Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers.OPTICAL MATERIALS,31(2),117-121. |
| MLA | Qiu, Xiaoming,et al."Study on a tetranuclear neodymium complex in polytrifluorochloroethylene oil for liquid lasers".OPTICAL MATERIALS 31.2(2008):117-121. |
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| Study on a tetranucl（219KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 请求全文 | |
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