Preparation and characterization of self-cleaning and anti-reflection ZnO-SiO2 nanometric films | |
其他题名 | 纳米ZnO-SiO2自清洁增透薄膜的制备及其性能 |
Guo Zhao-Long1,2; Zhao Hai-Xin1; Zhao Wei1 | |
作者部门 | 瞬态光学技术国家重点实验室 |
2016-03-20 | |
发表期刊 | ACTA PHYSICA SINICA |
ISSN | 1000-3290 |
卷号 | 65期号:6 |
产权排序 | 1 |
摘要 | Unlike the general anti-reflection and self-cleaning film such as SiO2 and TiO2-SiO2, the ZnO-SiO2 nanometric film used as a substrate of excellent transparency in visible region and effective photo-catalytic self-cleaning under UV illumination is seldom studied in the application as a substrate; however, it has a lot of advantages including high transmittance and low refractivity. In this paper, a self-cleaning and anti-reflection ZnO-SiO2 nanometric film is successfully fabricated by using a sol-gel dip-coating method. The morphology, crystal structure, surface microstructure and light transmittance of the obtained products are characterized by techniques such as TEM, SAD, XRD, SEM, DTA and UV-vis. Photo-catalytic degradation of the methylene blue (MB) in aqueous solution is used as probe reaction to evaluate the photo-catalytic activity of ZnO-SiO2 nanometric film. The TEM images reveal that the as-prepared ZnO nanoparticles are spherical grains with diameters of 12-20 nm, the average grain diameter is about 14.51 nm. ZnO nanoparticles obtained are of hexagonal wurtzite structure revealed by XRD pattern and there exist no other diffraction peaks. Furthermore, the SAD results show that ZnO microstructurs have good crystallinity. In addition, the ZnO grain size is about 14.41 nm by using the Scherrer formula calculation, which is consistent with the TEM results by the Gauss simulation. The UV-vis spectra reveal that the ultraviolet characteristic absorption peak of ZnO-SiO2 composite films is located at 368 nm and 375 nm after annealing at different temperatures such as 300 degrees C and 450 degrees C, corresponding to the band gaps of 3.37 eV and 3.31 eV, respectively. It is highly consistent with that obtained from pure ZnO nanoparticles. Increasing the annealing temperature results in a lower refractive index and the increases of the porosity in of the ZnO-SiO2 composite films. It has a uniformly refractive index value about 1.23-1.25 and a high porosity value about 50.3%-54.7% when the annealing temperature is 450 degrees C. Experimental results show that the ZnO-SiO 2 composite film can enhance the light transmittance of the quartz substrate, due to its lower reflective index and higher porosity. Compared with the quartz substrate, the average optical transmission rate of the quartz glass coated with ZnO-SiO 2 composite films is increased by about 4.17% at 400-800 nm, which favors greatly anti-reflection characteristics in a wide spectrum range. Meanwhile, the ZnO-SiO2 composite films are found to be efficient for photo-catalytically degradation of methylene blue dye under UV illumination, which favors greatly the self-cleaning function. |
文章类型 | Article |
关键词 | Nano Zno Sio2 Film Sol-gel Photo-catalytic |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.7498/aps.65.064206 |
收录类别 | SCI ; EI |
关键词[WOS] | THIN-FILMS ; ZNO ; SURFACE |
语种 | 中文 |
WOS研究方向 | Physics |
项目资助者 | Science and Technology Research and Development of Shaanxi Province, China(S2014GY2700) ; Science and Technology Plan of Innovation of Shaanxi Province, China(2015KTCQ01-63) ; Science and Technology Project of Xi'an, China(GX14021-05) |
WOS类目 | Physics, Multidisciplinary |
WOS记录号 | WOS:000380354000020 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.opt.ac.cn/handle/181661/28228 |
专题 | 瞬态光学研究室 |
作者单位 | 1.Chinese Acad Sci, Xian Inst Opt & Precis Mech, State Key Lab Transient Opt & Photon, Xian 710119, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Guo Zhao-Long,Zhao Hai-Xin,Zhao Wei. Preparation and characterization of self-cleaning and anti-reflection ZnO-SiO2 nanometric films[J]. ACTA PHYSICA SINICA,2016,65(6). |
APA | Guo Zhao-Long,Zhao Hai-Xin,&Zhao Wei.(2016).Preparation and characterization of self-cleaning and anti-reflection ZnO-SiO2 nanometric films.ACTA PHYSICA SINICA,65(6). |
MLA | Guo Zhao-Long,et al."Preparation and characterization of self-cleaning and anti-reflection ZnO-SiO2 nanometric films".ACTA PHYSICA SINICA 65.6(2016). |
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